- 周 祥,李玉香,鄭 召,馬 雪,倪 倩
2017年第1期
摘要
引用本文
摘??要:為了實現粉煤灰的高效利用,通過旋風分級機將原狀粉煤灰分成D50=5.06μm、15.63μm、35.01μm三個不同的粒度區間。不同粒度粉煤灰按照0、10%、20%和30%替代硅酸鹽水泥。研究了粉煤灰粒度對水泥膠砂強度和水化性能的影響。結果表明,隨著粉煤灰粒徑的減小,粉煤灰水泥的各齡期強度都逐漸增加,摻入適量細粒度粉煤灰,水泥各齡期膠砂強度超過了硅酸鹽水泥;粉煤灰水泥的水化放熱速率和累積放熱量都低于硅酸鹽水泥,隨著粉煤灰粒徑的減小,粉煤灰水泥的水化放熱速率和累積放熱量增加。3d齡期時,粉煤灰水泥漿體Ca(OH)2峰強度與硅酸鹽水泥幾乎相同;60d齡期時,隨著粉煤灰顆粒粒徑的減小,粉煤灰水泥漿體Ca(OH)2峰的強度明顯減??;SEM-EDS分析表明,細粒度區間的粉煤灰水泥漿體比粗粒度區間的粉煤灰水泥漿體具有更致密的漿體結構且粉煤灰顆粒水化生成的是一種低Ca/Si的C-S-H凝膠。Abstract:Toachievethehighefficientutilizationofflyash,alowcalciumoriginalflyashwasclassifiedinto3fractionsbyanairclassfier,withmedianparticlesizeof5.06μm,15.63μm,35.01μm,respectively.ThreesizesofflyashwereusedtopartiallyreplacePortalandcementat0,10%,20%and30%byweight.Theeffectofsizefractiononstrengthandhydrationpropertyofflyash-cementcomplexcementitiousmaterialsincorporatingflyashwasstudied.Testresultsindicatedthatwiththedeclineinthesizeofflyash,thestrengthofflyash-cementmortarsincreased.AndcementwithappropriatecontentoffineflyashshowedhigherstrengththanPortlandcementateveryage.TheheatevolutionresultsshowedthattherateofheatevolutionandcumulativeheatoftheflyashcementwerelowerthanPortlandcement.Withthedeclineinthesizeofflyash,therateofheatevolutionandcumulativeheatoftheflyashcementincreased.TheX-raydiffraction(XRD)resultsshowedthattheintensitypeaksofCa(OH)2offlyashcementwerealmostsimilartoPortlandcementat3days.However,withthedeclineinthesizeofflyash,theintensitypeaksofCa(OH)2offlyashcementdecreasedobviouslyat60days.Thescanningelectronmicroscope(SEM-EDS)resultsrevealedthatthehardenedblendedcementpastecontainingfinerflyashproducedadenserstructureandthesurfaceofflyashproducedC-S-HgelwithlowCa/Simolarduringpozzolanicreaction.
周祥,李玉香,鄭召,等.低鈣粉煤灰粒度對水泥-粉煤灰復合膠凝材料力學性能與水化性能的影響[J].混凝土與水泥制品,2017(1):1-7.
ZHOU X,LI Y X,ZHENG Z,et al.Influence of Size Fraction of Low Calcium Fly Ash on Mechanical Performance and Hydration Properties of Cement-fly Ash Composite Gel Materials[J].China Concrete and Cement Products,2017(1):1-7.