- 耿剛強1,張亞明1,畢偉濤2,曾二龍1,馬瑞杰2
2012年第11期
摘要
引用本文
摘??要:以道路修補灌漿料指標作為評價標準,采用含有高活性基團(-NCO)的異氰酸酯(TDI)作為中間體改性環氧樹脂,制備高性能水泥路面裂縫修補灌漿材料。研究結果表明,改性后的環氧樹脂路面修補材料的吸水率、收縮率、熱穩定性、力學性能、耐老化性等指標提高了20%以上,其綜合性能超過同等水泥裂縫修補材料。紅外光譜分析表明,有機硅成功接枝到了環氧樹脂上。掃描電鏡觀察表明斷面呈現韌性斷裂形貌。?Abstract:Takingroadrepairgroutingmaterialindexasevaluationstandard,usingisocyanate(TDI)whichcontainshighactivemoiety(-NCO)astheintermediatemodifiedepoxyresin,thehighperformancecrackrepairgroutingmaterialforcementpavementisprepared.Researchresultsshowthattheabsorptionrate,shrinkagerate,thermalstability,mechanicalproperty,agingresistanceindexofthemodifiedepoxyresinmendingmaterialisimprovedbymorethan20%,itscomprehensiveperformanceisbetterthanthesamecementcrackrepairmaterials.Theinfraredspectroscopyshowsthatsiliconesuccessfullygraftedontoepoxyresin,andthescanningelectronmicroscopeshowsthatthesectionpresentsductilefracturemorphology.